Chopping an onion breaks open its cells. Enzymes that were kept apart suddenly meet sulfur-rich compounds, and the mix creates a volatile gas called syn-propanethial-S-oxide.1
That gas drifts up to your eyes. On the moist surface of the eye it forms a mild acid, so your brain triggers tears to rinse the irritant away.2 The cascade is a two-step enzyme path: alliinase starts the sulfur chemistry, then lachrymatory-factor synthase builds the tear gas itself.3
Onions use the gas as a defense against animals — botanical warfare that only starts once something cuts into the bulb.4 Cooling the onion before you chop slows the enzymes and softens the sting.
Image material: A person cutting an onion
References
- 1Why Do Onions Make You Cry?
britannica.com
- 2Propanethial-S-oxide: how chopping onions makes you cry
chemistryworld.com
- 3
- 4syn-Propanethial S-oxide
acs.org


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